Synthesis and preliminary analytical evaluation of the chemiluminescence from (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2 2'-bipyridyl)bis(2 2'-bipyridyl))ruthenium(II) covalently bonded to silica particles

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dc.contributor.authorBarnett, N.
dc.contributor.authorBos, R.
dc.contributor.authorBrand, H.
dc.contributor.authorJones, P.
dc.contributor.authorLim, K.
dc.contributor.authorPurcell, S.
dc.contributor.authorRussell, R.
dc.date.issued2002
dc.descriptionCopyright © 2002 Royal Society of Chemistry
dc.description.abstractThis paper describes, for the first time, a simple and effective synthetic route for covalently bonding the chemiluminescence reagent, (4-[4-(dichloromethylsilanyl)-butyl]-4-methyl-2,2-bipyridyl)bis(2,2-bipyridyl)ruthenium(II) onto silica particles. The subsequent preparation of chemically regeneratable detection cells and their preliminary analytical evaluation with both sequential injection analysis and flow injection analysis are also reported. Unoptimised analytical figures of merit were established for standard solutions of codeine and sodium oxalate with detection limits calculated from three times the standard deviation of the blank signal, of 1 × 10–8 M and 3 × 10–7 M respectively. The chemically immobilised reagent exhibited some intriguing solvent and kinetic effects, which are also briefly discussed.
dc.description.statementofresponsibilityNeil W. Barnett, Richard Bos, Holger Brand, Philip Jones, Kieran F. Lim, Stuart D. Purcell and Richard A. Russell
dc.identifier.citationThe Analyst, 2002; 127(4):455-458
dc.identifier.doi10.1039/b200794k
dc.identifier.issn0003-2654
dc.identifier.issn1364-5528
dc.identifier.urihttp://hdl.handle.net/2440/48131
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.source.urihttp://pubs.rsc.org/en/Content/ArticlePDF/2002/AN/B200794K/2002-02-27
dc.titleSynthesis and preliminary analytical evaluation of the chemiluminescence from (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2 2'-bipyridyl)bis(2 2'-bipyridyl))ruthenium(II) covalently bonded to silica particles
dc.typeJournal article
pubs.publication-statusPublished

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