Structural reassignment of Cytosporolides A - C via biomimetic synthetic studies and reinterpretation of NMR data
Date
2011
Authors
Spence, J.
George, J.
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Journal article
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Organic Letters, 2011; 13(19):5318-5321
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Justin T. J. Spence and Jonathan H. George
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Abstract
A structure revision for the recently isolated fungal meroterpenoids, cytosporolides A-C, is suggested based on biosynthetic speculation and reinterpretation of existing spectroscopic data. The structure revision is supported by a biomimetic synthetic study, featuring a [4 + 2] cycloaddition reaction between a presumed o-quinone methide intermediate and β-caryophyllene.
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© 2011 American Chemical Society