Structural reassignment of Cytosporolides A - C via biomimetic synthetic studies and reinterpretation of NMR data

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dc.contributor.authorSpence, J.
dc.contributor.authorGeorge, J.
dc.date.issued2011
dc.description.abstractA structure revision for the recently isolated fungal meroterpenoids, cytosporolides A-C, is suggested based on biosynthetic speculation and reinterpretation of existing spectroscopic data. The structure revision is supported by a biomimetic synthetic study, featuring a [4 + 2] cycloaddition reaction between a presumed o-quinone methide intermediate and β-caryophyllene.
dc.description.statementofresponsibilityJustin T. J. Spence and Jonathan H. George
dc.identifier.citationOrganic Letters, 2011; 13(19):5318-5321
dc.identifier.doi10.1021/ol202181g
dc.identifier.issn1523-7060
dc.identifier.issn1523-7052
dc.identifier.orcidGeorge, J. [0000-0002-7330-2160]
dc.identifier.urihttp://hdl.handle.net/2440/70984
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.rights© 2011 American Chemical Society
dc.source.urihttps://doi.org/10.1021/ol202181g
dc.subjectSesquiterpenes
dc.subjectMagnetic Resonance Spectroscopy
dc.subjectMolecular Structure
dc.subjectCyclization
dc.subjectBiomimetic Materials
dc.subjectPolycyclic Sesquiterpenes
dc.titleStructural reassignment of Cytosporolides A - C via biomimetic synthetic studies and reinterpretation of NMR data
dc.typeJournal article
pubs.publication-statusPublished

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