Chiral amide from (1S,2R)-(+)-norephedrine alkaloid in the enantioselective addition of diethylzinc to aryl and heteroaryl aldehydes
Date
2009
Authors
Ananthi, N.
Balakrishnan, U.
Vinu, A.
Ariga, K.
Velmathi, S.
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Journal article
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Tetrahedron: Asymmetry: the international journal for rapid publication on all aspects of asymmetry in organic, inorganic, organometallic, physical and bioorganic chemistry, 2009; 20(15):1731-1735
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Abstract
Chiral amide synthesized from (1S,2R)-(+)-norephedrine and furoic acid was found to catalyze the enantioselective ethylation of aromatic and heteroaromatic aldehydes to secondary alcohols with 99.8% enantioselectivity at 0 °C without the addition of a promoter such as titanium tetraisopropoxide.
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Copyright 2009 Elsevier.