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Chiral amide from (1S,2R)-(+)-norephedrine alkaloid in the enantioselective addition of diethylzinc to aryl and heteroaryl aldehydes

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dc.contributor.authorAnanthi, N.
dc.contributor.authorBalakrishnan, U.
dc.contributor.authorVinu, A.
dc.contributor.authorAriga, K.
dc.contributor.authorVelmathi, S.
dc.date.issued2009
dc.description.abstractChiral amide synthesized from (1S,2R)-(+)-norephedrine and furoic acid was found to catalyze the enantioselective ethylation of aromatic and heteroaromatic aldehydes to secondary alcohols with 99.8% enantioselectivity at 0 °C without the addition of a promoter such as titanium tetraisopropoxide.
dc.identifier.citationTetrahedron: Asymmetry: the international journal for rapid publication on all aspects of asymmetry in organic, inorganic, organometallic, physical and bioorganic chemistry, 2009; 20(15):1731-1735
dc.identifier.doi10.1016/j.tetasy.2009.07.011
dc.identifier.issn0957-4166
dc.identifier.urihttps://hdl.handle.net/11541.2/112212
dc.language.isoen
dc.publisherPergamon Press
dc.relation.fundingMinistry of Education, Culture, Sports, Science and Technology (MEXT)
dc.relation.fundingWorld Premier International Research Center (WPI) Initiative on Materials Nanoarchitectonics, MEXT
dc.relation.fundingDST SR/ FTP/CS-142-2006
dc.rightsCopyright 2009 Elsevier.
dc.source.urihttps://doi.org/10.1016/j.tetasy.2009.07.011
dc.subject2 furoic acid
dc.subjectnorephedrine
dc.subjecttitanium derivative
dc.subjecttitanium tetraisopropoxide
dc.subjectunclassified drug
dc.titleChiral amide from (1S,2R)-(+)-norephedrine alkaloid in the enantioselective addition of diethylzinc to aryl and heteroaryl aldehydes
dc.typeJournal article
pubs.publication-statusPublished
ror.mmsid9915986309701831

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